The tail post (trailing edge of the vertical stabilizer) and the firewall should be perpendicular to the longitudinal axis. Make those vertical and it will be ready, (read that level), to weigh. Scales under the mains and one under the tailwheel. You can get your moment arms from the TCDS.
IMHO it seems best to use the factory leveling means, and factory datum. From the PA18 TCDS # 1A2 :
"datum: wing leading edge
leveling means: plumb from PK screw in upper door frame channel to center punch mark on enclosure door rear hinge".
If there isn't a PK screw (hole) and /or centerpunch mark,
I believe there's a factory drawing showing how to level the plane,
using the "horizontal reference line" & a water level (or laser).
I know a couple different people who had airplanes on which the firewall & the tail post weren't quite parallel,
they ended up using the reference drawings to level their airplane.
This sheet explains the preferred (factory" means of leveling, as well as an alternate method:
Also, in my experience, it's best to physically plumb down & measure the arms for various moments,
as what's on the TCDS doesn't always necessarily agree with the actual airplane.