Charlie is correct. Electrons flow from negative to positive.
IF: the only problem at the moment is the 'instrument breaker popping when turning the key to the 'start' position, then stop throwing parts at it. If that breaker is the only one popping then it has to be a circuit connected to that breaker.
Disconnect all circuits, from that breaker, except the starter circuit and check to see if it pops.
If NO, then one of the disconnected circuits is the problem.
If YES, troubleshoot the starter circuit.
Just opinion here, but I'm going to say that there is a problem with the start circuit. It's easy to troubleshoot. Power wire from the 'instrument breaker to the 'B' terminal on the key switch. Then a wire from the 'S' terminal on the key switch to one of the small terminals on the start relay, with the other small terminal tied to airframe ground. Check for a short on the wire from key switch to start relay. If that's good, replace the diode that was installed backwards on the start relay .:lol:
Just from past observations, this isn't the only problem here. Every single item on that bus, that has a diode or chip installed, is going to be suspect. And even if it works now, some of them are going to fail in a short time.
Bad things happen when them 'trons stampede in the wrong direction.
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