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Oil analysis and sticking exhaust valve?

This is interesting. One recent conversation about oil it was mentioned that the 'plus' additive, a fairly new thing, is much better for your engine than the older versions. I was told that one could run the 'plus' oil, or run an additive like Cam Guard which amounts to the same thing.

I believe when I get my new engine I will be going back to strait weight oils. Used it on the cub for years...

Thank you for the information and experience; did you need a new seat cushion?

The new Phillips stuff is basically just the Lycoming slick 50 additive used to prevent excessive cam/lifter wear.
DENNY
 
"Cooler spark" A cool plug has a shorter center insulator so the plug runs cooler, not the engine or combustion. Fine wire plugs resist fouling in spite of running cool(or oily) they don't change anything.
 
At some point in this discussion I am hoping we have a chemist.

With the change in base metals used in fuels over the last few decades, and the changes in oil additives, is it possible that we have some chemical reaction that is increasing the valve sticking problem?
 
...With the change in base metals used in fuels over the last few decades, and the changes in oil additives, is it possible that we have some chemical reaction that is increasing the valve sticking problem?

That's sorta' what I asked in #25...has valve sticking in GenAv always been a problem? How about the 1950's and '60's? Anyone recall that flew then? I didn't have a problem (valve sticking/cams) until the mid-'80's and that was when I switched to a multi-vis 15W-50 in small Lycomings. The Conti IO-520's I flew ran TBO one after the other but on straight weight.

Gary
 
I know there are folks who are not a fan of Mike Busch on this forum. The dude admits he is more of a data analyst. Points of random data exists. If we can organize the data, then we have information. If we read the information, we can gain knowledge and which leads to wisdom....or maybe leads to improved reliability of Lycoming engines. It seems to me like Engine Data analysis is Mikes strong suite. The facts below are his, not mine. Below is a synopsis of the data Mike shares in that video link in post 28 and this AOPA article
https://www.aopa.org/news-and-media/all-news/2020/july/pilot/savvy-maintance-valves

-Cool running engines have more sticky valves than warmer running engines.

-Valves stick due to buildup of deposits on the valve stem inside of the valve guide.

-Laboratory chemical analysis by a petrochemist from Exxon has been performed on valve stems.

-TEL is used as an octane booster in 100LL fuel requires a scavenging agent.

-This lead scavenging agent that is added to help avoid fouled spark plugs.

-A chemical reaction during the combustion event produces a byproduct of the scavenging agent called Lead OxiBromide.

-The Lab analysis showed that Lead OxiBromide is primarily the source of the buildup on the stems of stuck valves.

-Engine Monitor will show a rough running engine from a sticking valve to produce an EGT value that is not normal. As the engine warms and the stuck valve loosens, the EGT will indicate normal.

-Lead Oxibromide that remains as a gas above temps of 1100F.

-After the combustion event we want the Lead OxiBromide to remain gaseous (above 1100F) to pass harmlessly out the exhaust.

-The hotter the temp, the faster the lead is scavenged.

-A cooler surface will condense these gases and over time form hard deposits on surfaces they contact, like a valve stem of an open exhaust valve.

-Sodium filled Lycoming valve stems run cooler than Continental valves and the chances of a stuck valve is more likely with them.

--Mike thinks that the conventional wisdom that the carbon deposits on the valve stem inside the valve guide from oil contacting the hot stem and carbonizing the oil is wrong.

What Mike says to do....

-Since CHT is the best indicator for Valve stem temperature, keep the CHT's between 350F - 400F to avoid Lead Bromide buildup on your valve stems.

-Lean aggressively on the ground and low power operations to keep combustion temps as high as possible.

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While there definitely has been a change in the metal alloys involved, it seems that the issues of sticking began as 80 oct began to disappear and more planes needed to start using 100/130 oct. Increased lead build up on the valve stems. When the 100/130 was discontinued and 100LL came upon the scene, the lead ppm was cut in half but was still more than the 80 oct. The wobble test was to indicate when excessive clearances between the valve and guides started appearing as an issue. A metallurgical issue.
 
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I know this is just an O-200, but when I got home and pulled the exhaust, this is what all 4 exhaust ports looked like. All the guides had crud, as did the seats. I operated this airplane for 20+ years before we overhauled the engine and never had a problem, maybe 2500 hours. After break in I ran the same we I always have, hard and lean. Again, this is from about 250 hours of operation.
 

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Ok thanks Pete for the historical perspective. Can we assume there's two problem scenarios (https://bondline.org/wiki/Valve_Wobble_Testing)? The valve to guide clearance increases via wear and is noted by the wobble test. Or, the valve to guide clearance decreases (and maybe after the previous scenario) due to deposit buildup. Both are not good.

Gary
 
"I know this is just an O-200, but when I got home and pulled the exhaust, this is what all 4 exhaust ports looked like. All the guides had crud, as did the seats. I operated this airplane for 20 years before we overhauled the engine and never had a problem, maybe 2500 hours. After break in I ran the same we I always have, hard and lean. Again, this is from about 250 hours of operation."

Was the oil consumption post break-in similar pre and post overhaul? Were the fuel and oil used the same?

Gary
 
Everything the same Gary, except probably slightly more 100LL post overhaul due to the Alaska trip. Harder to find mogas enroute. Trusted engine shop said he suspected improperly ground seats. He said he never installs new cylinders anymore without checking as he’s seen way to many. If I have any more problems I’ll pull the cylinders and take them to him.
 
Everything the same Gary, except probably slightly more 100LL post overhaul due to the Alaska trip. Harder to find mogas enroute. Trusted engine shop said he suspected improperly ground seats. He said he never installs new cylinders anymore without checking as he’s seen way to many. If I have any more problems I’ll pull the cylinders and take them to him.

Mark,

Do you run TCP? Auto fuel?

Kurt
 
I know there are folks who are not a fan of Mike Busch on this forum. The dude admits he is more of a data analyst. Points of random data exists. If we can organize the data, then we have information. If we read the information, we can gain knowledge and which leads to wisdom....or maybe leads to improved reliability of Lycoming engines. It seems to me like Engine Data analysis is Mikes strong suite. The facts below are his, not mine. Below is a synopsis of the data Mike shares in that video link in post 28 and this AOPA article
https://www.aopa.org/news-and-media/all-news/2020/july/pilot/savvy-maintance-valves

-Cool running engines have more sticky valves than warmer running engines.

-Valves stick due to buildup of deposits on the valve stem inside of the valve guide.

-Laboratory chemical analysis by a petrochemist from Exxon has been performed on valve stems.

-TEL is used as an octane booster in 100LL fuel requires a scavenging agent.

-This lead scavenging agent that is added to help avoid fouled spark plugs.

-A chemical reaction during the combustion event produces a byproduct of the scavenging agent called Lead OxiBromide.

-The Lab analysis showed that Lead OxiBromide is primarily the source of the buildup on the stems of stuck valves.

-Engine Monitor will show a rough running engine from a sticking valve to produce an EGT value that is not normal. As the engine warms and the stuck valve loosens, the EGT will indicate normal.

-Lead Oxibromide that remains as a gas above temps of 1100F.

-After the combustion event we want the Lead OxiBromide to remain gaseous (above 1100F) to pass harmlessly out the exhaust.

-The hotter the temp, the faster the lead is scavenged.

-A cooler surface will condense these gases and over time form hard deposits on surfaces they contact, like a valve stem of an open exhaust valve.

-Sodium filled Lycoming valve stems run cooler than Continental valves and the chances of a stuck valve is more likely with them.

--Mike thinks that the conventional wisdom that the carbon deposits on the valve stem inside the valve guide from oil contacting the hot stem and carbonizing the oil is wrong.

What Mike says to do....

-Since CHT is the best indicator for Valve stem temperature, keep the CHT's between 350F - 400F to avoid Lead Bromide buildup on your valve stems.

-Lean aggressively on the ground and low power operations to keep combustion temps as high as possible.

View attachment 52176


Thanks for that info. Did he comment on TCP and if it was good or bad concerning valve sticking?

Kurt
 
Thanks for that info. Did he comment on TCP and if it was good or bad concerning valve sticking?

Kurt

According to this article TCP does nothing for sticky valves.
 

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The chemistry tutorial above is courtesy of CamGuard. Note the short time (as little as 15-20 hrs) they suggest additives become depleted and the nastiness begins. If so, why fly 50 hrs on an oil....unless you use their product?

Gary
 
Through the years one of the aviation writer voices I've trusted is Ben Visser. He continues to advocate the use of leaded fuel in aircraft engines but continues to use 25% leaded to unleaded as a blend recommendation for breaking an engine in and occasional addition of leaded fuel throughout the engine's life. His reasoning centers around valve recession and valve heat transfer. In my own airplane ownership history valve recession and erosion has occurred in my engines. Valve sticking has not.

I see evidence of accumulated exhaust crud on my shocks and remove it regularly. I assume lead is a big component of this crud. I plan to blend in some unleaded fuel to see if I recognize a reduction in the exhaust deposits. I don't have the knowledge or tools to do any important testing to find my perfect fuel so I'll err to the lead-rich side with my 10:1 cylinders. I'm not focused on valve sticking. I want the best fuel for the entire engine.
 
I run both auto and 100LL, depending on what I can get. I’ve never run any fuel additives, but now I am using mmo.

If valve sticking is the problem a little MMO in the oil may be useful. I've been told that's where it got it's start with airplanes. Subsequently an engine build shop owner told me a little MMO in the oil is the first thing a pilot should do for suspected morning sickness. It may not be a long term solution but it should buy time.

I routinely added MMO into my bulk fuel tank until talking to Mr Camguard about airplane engines and additives. He told me (this was over 10 years ago) that the MMO formula changed somewhere around 2000 and now contains a chlorinated something something and that was bad news for rubber and synthetic rubber. He didn't give its use much merit and said now it could actually do more harm than good. Since my 180 has bladder tanks I took his comments to heart and stopped using MMO. I can't recognize any difference in my engines.

MMO is primarily a mixture of mineral spirits (Stoddard solvent) and light oil with some other magic smells and colors added. In the lead scavenging discussion which of those components is providing the benefit? Mr Camguard suggested that if I believed MMO was helpful I could mix my own and leave out the bad stuff. FWIW Seafoam fuel treatment is a similar mineral spirits/oil product with isopropyl added. Anyone using that?
 
I do run camguard. I used to read the threads about sticking valves and additives and be thankful I didn’t have to deal with that. Then, overhaul with all new parts including cylinders and here I am. Hard to accept that I ran for so long with zero issues, have changed nothing in how I operate and now seeing these problems. I’ll have to look into the MMO issue, thanks.
 
Great discussion! I thought, (maybe incorrectly) that engine start wasn’t recommended under 40*f if you were running straight 100w. Wrong? I run the Phillips 20/50 w/Camgaurd and I use MMO in the gas and fly about 200hrs/yr. I did develop low comp on one cyl last year (50/80) from a leaking exhaust valve. The valve guide was replaced now all 4 are running 78/80 but don’t believe that had anything to do with the oil. What about engine start at temps below 40*f?
 
I do run camguard. I used to read the threads about sticking valves and additives and be thankful I didn’t have to deal with that. Then, overhaul with all new parts including cylinders and here I am. Hard to accept that I ran for so long with zero issues, have changed nothing in how I operate and now seeing these problems. I’ll have to look into the MMO issue, thanks.

Is it at all possible that these new cylinders are running cooler than the TCM cylinders? Better Baffling? Do you have an engine monitor?
 
Yes, that’s one of our thoughts. We built new cowling and all new baffling when we hung the engine. No engine monitor but we are going to try and rig something up to check temps. Thanks for the input..
 
My two cents. I did a top overhaul on my engine and used the Phillips 20-50XC as recommended for break in by the cylinder company. The good thing about this is you can just keep running the Phillips after break in. At around 250 hours on the cylinders on a trip to Alaska I had a sticking valve out of Dease Lake. That will get your attention real quick! I came back and landed and looked things over but did not know what was going on since I had never experienced this before. I could not duplicate it and continued on. I got to Ultima Thule Lodge and had it happen again one morning. I told Paul about it and he said it sounds like a valve sticking and asked what engine oil I was using. He told me he only runs straight weight Aeroshell and told me to change oil. I continued fighting this sticking valve for another 100 hours thinking how could it be the oil and I had a few cases of oil to use. It seemed if I did a long through warm up I did not usually have a problem, then one day coming through the gorge on top and it started doing it after a flight back from Idaho and I decided this has got to be fixed. I switched oil to Aeroshell 100 plus and it never did it again. I will never use Phillips again.

Ok in the interest of completely muddying the water on what I wrote a few days back (see above). I was talking to Loni Habersetzer today about engine oil, he flies for Paul Claus and his engines go to TBO and beyond. I was telling him my experience with Phillips and what Paul had told me about just using straight weight Aeroshell. He fired back that Ultima Thule Airplanes all run Phillips 20-50XC now and have for at least 6-7 years since Paul asked him (Loni) what engine oil he uses because he had no problems ever making TBO. I asked Loni if he has ever had a stuck valve he said no. I will continue with my use of straight weights but here is evidence that maybe just believing in something can make it better:lol:
 
Ok, is not flying the airplane 6 months a year as Ultima Thule does (when there season is over) consider as frequent or infrequently. They fly 6 months daily and then not at all for 6 months, airplanes are hangard.
 
Are the hangars heated in the off season? Edit: If they are heated above freezing find out what steps they take to reduce or prevent corrosion when sitting idle. Might be worth knowing.

Gary
 
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If you read all the posts it is a total crapshoot on what seems to work and what does not. Flying daily/weekly does seem to help for lifter/cam issues. Valve sticking is all over the board. I think one of the issues is what lean, hot, often to one person is not the same to another. Bottom line is when you notice a change even for a few seconds look into it. I do like all the information that people post because it actually has some science behind it!!
DENNY
 
From what I've seen here and in other Forums, periodic borescoping and valve cover removal (with pics recorded over time) might help show a trend in valve condition and the buildup of visible deposits. I'm not an expert in either. I do know it's a good idea to have uniform valve to seat contact to dissipate valve heat, and valve to guide inspection (visual/wobble test) can detect deposits. Some of the valve stem blow-by deposits can coat the exposed valve and springs plus the inside of the adjacent valve cover. If it becomes apparent then maybe there's a problem to be addressed. We try to keep the costs down and add a prevention step but maybe this would be worth doing?

Gary

Edit: I found this lengthy video on using a borescope in an aircraft application: https://www.youtube.com/watch?v=Dk5o4__0y-4 Guess i'll learn something tomorrow.
 
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I’m curious to see if anyone else has noticed a trend in their oil analysis and sticking exhaust valves. I would occasionally get a slight shutter during cruise ever since my trip to Idaho in May. I just thought the engine was digesting some water since I had pulled a small amount of water out of the fuel tank when I sumped it during preflight. I only pulled water out once though. I just did a trip to Utah last month and I was getting some morning sickness on the first start-up and that was the first time I’d had any issues on start up. I was probably in denial but I attributed it to the high altitude and cold weather. I had a couple of more shutters on the last leg home and then the the valve finally stuck for good on the first start up after my trip when I went to warm up the oil for an oil change. I certainly learned some lessons with what a sticking exhaust valve feels like now. My oil analysis had been showing high chrome which initially we thought was because the engine sat for five years during restoration and had some corrosion but it got worse as I ran the engine. I’ve attached my latest oil analysis to see if anyone has any ideas if there were clues to my sticking valve from that. It was the number 3 cylinder on a O-320A2B 160hp. I use Phillips XC 20W50 with Camguard, and I don’t used MMO in the fuel or oil. The engine was built in 1982, had 1600 hours on it, and was never overhauled. It’s now at LyCon getting getting it’s long awaited overhaul. Don’t be like me and let it get this far when you get morning sickness. I’m extremely fortunate that the valve decided to stick for good after I got home and not on my trip.
After seeing the recent dyno numbers from Jason’s freshly overhauled, fire breathing post stuck valve engine I’m thinking I also need a stuck valve and bent pushrod:p
 
After seeing the recent dyno numbers from Jason’s freshly overhauled, fire breathing post stuck valve engine I’m thinking I also need a stuck valve and bent pushrod:p

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Why not follow Lycoming's guidance? They allow around 400 CHT and they have a 400hr valve inspection written in the maintenance manual, operators manual, and encase you missed it they also published it in a Si, and a mandatory SB, if I am not mistaken. Yet, how many of us educated owners bother with it? Worse yet, how many FAA shops know about it or provide the required "push" to educate the owners about it? I know, if I fly part 91 I don't have to, but in some things it is in our best interests. I think that may be the case here.

larry
 
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